论文成果
Influence of electric field on the viscosity of waxy crude oil and micro property of paraffin: A molecular dynamics simulation study
摘要:Electrical treatment is a useful method for reducing viscosity of waxy crude oil. Molecular dynamics simulation was employed to study the influence of electric field on viscosity of waxy crude oil and micro properties of paraffin. The waxy crude oil model consists of light oil and 24.9% by weight of paraffin. The simulation results show that viscosity decreases when electric field is applied. The larger the electric field intensity, the greater the decreasing extent of viscosity. The electrical viscosity-reducing effect is better at lower temperatures. The radial distribution function and diffusion coefficient were analyzed for explaining the reason of viscosity decreasing. The radial distribution function results confirm that electric field promotes aggregation of paraffin molecules. Diffusion coefficient increases with the increase of electric field intensity. At the same temperature, the higher the electric field strength, the larger the increasing extent of diffusion coefficient. In a certain electric field intensity, the lower the temperature, the greater the increasing extent. The changing tendency of diffusion coefficient is consistent with the trend of viscosity reduction under electrical treatment. It is suggested that the change of diffusion coefficient is the main reason for electrical viscosity-reducing effects, the contribution of aggregation is smaller than increasing of diffusion coefficient.
© 2018 Elsevier B.V.
ISSN号:0167-7322
卷、期、页:v 272,p973-981
发表日期:2018-01-01
影响因子:3.648000
期刊分区(SCI为中科院分区):三区
发表期刊名称:Journal of Molecular Liquids
通讯作者:陈雪娇,李文超,李师瑶
第一作者:侯磊
论文类型:期刊论文
论文概要:陈雪娇,侯磊,李文超,李师瑶,Influence of electric field on the viscosity of waxy crude oil and micro property of paraffin: A molecular dynamics simulation study,Journal of Molecular Liquids,2018,v 272,p973-981
论文题目:Influence of electric field on the viscosity of waxy crude oil and micro property of paraffin: A molecular dynamics simulation study