摘要：Gas hydrate inhibitors are employed to mitigate gas hydrate formation in pipelines. The effects of thermodynamics inhibition were evaluated by measuring the vapor - liquid aqueous solution - solid hydrate (VLH) equilibrium conditions on methane (CH4) hydrate in the presence of three organic carboxylic sodium salts (sodium formate, sodium acetate, sodium propionate) in this study. The experiments were carried out in the temperature range of 273.65 K to 281.65 K. Compared with deionized water, in the electrolyte solutions of sodium formate, sodium acetate and sodium propionate with mole fraction of 0.010 and 0.020, the VLH equilibrium pressure change (ΔP) increased by 12.93, 27.68 %; 18.78, 38.15 %; 23.51, 49.41 %, respectively. Both of the three organic carboxylic sodium salts have obvious thermodynamic inhibition effect on CH4 hydrate. The strength of hydrate inhibition is related to the carbon chain length of organic carboxylate. The dissociation enthalpy (ΔHdiss) of CH4 hydrate in three organic carboxylic sodium salts solutions remains quite uniform with deionized water, which indicates that three organic carboxylic sodium salts have not been involved in the formation of hydrate nucleus. The Chen-Guo hydrate model and N-NRTL-NRF activity model were employed to predict the VLH equilibrium conditions in electrolyte solutions. In the three organic carboxylic sodium salts solutions, the average absolute relative deviations (AARD) of the VLH equilibrium condition data between the predicted and the experimental were 0.81, 2.17, and 3.02 %, respectively. In the sodium chloride (NaCl) and potassium chloride (KCl) solutions, the AARD between the predicted and literature were 1.44, 1.69 %, respectively. The model has good universality and accuracy. Both sodium acetate and sodium propionate are food grade preservatives. Consequently, these are beneficial for the development of environmental-friendly hydrate inhibitors. ? 2023

ISSN号：0021-9614

卷、期、页：卷180

发表日期：2023-05-01

影响因子：0.000000

期刊分区（SCI为中科院分区）：二区

收录情况：EI（工程索引）

发表期刊名称：Journal of Chemical Thermodynamics

第一作者：徐振,王逸伟,阚京玉,刘爱贤,孙强,陈建义,郭绪强

论文类型：期刊论文

论文概要：徐振,王逸伟,阚京玉,刘爱贤,孙强,陈建义,郭绪强，Experimental measurement and model prediction on methane hydrate equilibrium conditions in the presence of organic carboxylic sodium salts，Journal of Chemical Thermodynamics，2023，卷180

论文题目：Experimental measurement and model prediction on methane hydrate equilibrium conditions in the presence of organic carboxylic sodium salts