论文成果
Study on the pyrolysis characteristics of sawdust catalyzed by spent FCC catalyst and blast furnace ash
摘要:Two industrial wastes, spent FCC catalyst (sFCCc) and blast furnace ash (BFA), were used as catalysts in the fast pyrolysis of sawdust, and the catalytic pyrolysis reaction characteristics of sawdust in the temperature range of 400?700 ℃ were explored. The results showed that both catalysts promoted the conversion from liquid products to gaseous products, and the highest gas yield was 52.60% at 700 ℃ catalyzed by BFA. The sFCCc had stronger deoxygenation activity at 500?600 ℃, resulting in higher CO and CO2 production in gaseous products. While BFA had higher polycondensation and dehydrogenation activity at 600?700 ℃, and promoted the formation of polycyclic aromatic compounds and H2. Pyrolysis oil was mainly composed of phenols. The sFCCc promoted the conversion of methoxy phenol to benzenediol. FT-IR analysis of pyrolysis oil showed that sFCCc promoted the removal of C?O and C=O, resulting in decreased acid and ester compounds and increased CO2 yield. ? 2022 Science Press. All rights reserved.
ISSN号:2097-213X
卷、期、页:卷50期11:1524-1534
发表日期:2022-11-01
期刊分区(SCI为中科院分区):无
收录情况:EI(工程索引)
发表期刊名称:Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology
参与作者:刘明华
通讯作者:乔沛,乔沛,李国通
第一作者:张玉明,李家州,张炜
论文类型:期刊论文
论文概要:张玉明,乔沛,乔沛,李国通,李家州,张炜,刘明华,Study on the pyrolysis characteristics of sawdust catalyzed by spent FCC catalyst and blast furnace ash,Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology,2022,卷50期11:1524-1534
论文题目:Study on the pyrolysis characteristics of sawdust catalyzed by spent FCC catalyst and blast furnace ash