摘要：Studies on clustering characteristics in aqueous solutions have increased considerably in the past dec-ades. Accurate knowledge of the clustering behavior of molecules or ions is the basis for understanding the anomalous properties in aqueous solutions, as well as for their applications in environmental engi-neering, energy utilization, and separation process. In this study, we primarily review the relevant exper-imental and simulation studies as well as modeling approaches of clustering behavior in aqueous solutions, including the structural characteristics, cluster populations, anomalous properties, and modern modeling approaches. A more detailed and in-depth understanding of clustering structures and distribu-tions can be available by using molecular simulation combined with the spectra data. The clustering pop-ulation, part of thermodynamic properties, and anomalous properties due to the clustering in aqueous solutions can be obtained by using modeling approaches coupled with experimental studies. Finally, we discuss the current challenges and perspectives for future research on the clustering behavior in aque-ous solutions. (c) 2022 Elsevier B.V. All rights reserved.

关键字：Clusters; Aqueous solution; Structural transitions; Spectra studies; Molecular simulation; Model

ISSN号：0167-7322

卷、期、页：卷: 367子辑: A

发表日期：2022-12-01

影响因子：6.165200

期刊分区（SCI为中科院分区）：二区

收录情况：SCIE（科学引文索引网络版）

发表期刊名称：JOURNAL OF MOLECULAR LIQUIDS

通讯作者：汤涵,蔡进

第一作者：朱晨阳,陈光进,王晓辉,孙长宇

论文类型：期刊论文

论文概要：汤涵,蔡进,朱晨阳,陈光进,王晓辉,孙长宇，Review on the clustering behavior in aqueous solutions，JOURNAL OF MOLECULAR LIQUIDS，2022，卷: 367子辑: A

论文题目：Review on the clustering behavior in aqueous solutions