摘要：Heterogeneous catalysts are usually constructed by immobilizing active species on appropriate supports. However, the dispersibility is difficult to precisely control. In this work, three representative Mo-based MOFs (Mo-MOFs) were constructed by assembling various organic linkers and MoO3, where the Mo atoms are homogeneously dispersed due to the coordination. The results illustrated that the obtained Mo-MOF-PI synthesized with 2-propyl imidazole as the ligands exhibited an extremely fast reaction rate, achieving 99.4% sulfur removal of DBT within only 12 min. Compared to other similar catalysts, Mo-MOF-PI showed much higher catalytic activity with a turnover frequency value of 19.2 h?1. Moreover, it can be reused at least 20 times without a dramatic reduction in catalytic performance. Thus, the as-prepared Mo-MOF catalysts show great potential in large-scale industrial applications. ? 2023 Elsevier B.V.

ISSN号：1383-5866

卷、期、页：卷326

发表日期：2023-12-01

影响因子：0.000000

期刊分区（SCI为中科院分区）：一区

收录情况：SCI（科学引文索引印刷版）,EI（工程索引）,SCIE（科学引文索引网络版）

发表期刊名称：Separation and Purification Technology

参与作者：Xu, Lingchao,An, Xin,She, Junfeng,Li, Hongping,Zhu, Linhua,Li, Huaming,Jiang, Wei

第一作者：朱文帅

论文类型：期刊论文

论文概要：Xu, Lingchao,An, Xin,She, Junfeng,Li, Hongping,Zhu, Linhua,朱文帅,Li, Huaming,Jiang, Wei，Molybdenum-based metal–organic frameworks as highly efficient and stable catalysts for fast oxidative desulfurization of fuel oil，Separation and Purification Technology，2023，卷326

论文题目：Molybdenum-based metal–organic frameworks as highly efficient and stable catalysts for fast oxidative desulfurization of fuel oil