摘要：Structured monolithic catalysts have attracted growing attention in the petrochemical industry due to significant advantages of reusability, easy scale-up, and high heat and mass transfer rate. 3D printing offers enormous flexibility in accurately regulating the configuration of monolithic catalysts to realize the strengthening of the reaction process. However, this remains challenging in terms of reliable manufacturing, high resolution, and the distribution of active sites. Here, we report a direct photo-curing 3D printing based method for manufacturing precise monolithic catalysts for oxidative desulfurization of fuels. Numerous molybdenum oxide nanoparticles with a high density of oxygen vacancies are spatially distributed in three-dimensional Al2O3 by 3D printing technology and post-treatment, thus favoring the catalytic reaction. This 3D-MoOx/Al2O3 exhibits excellent catalytic performance with a 99.2 % conversion of dibenzothiophene. Furthermore, this tailored catalyst is 3Dprinted to manufacture a monolithic agitating impeller as a stirring reactor, which plays a dual role in mixing and catalysis. The study provides an effective strategy for precisely manufacturing structured catalysts with excellent catalytic activity and can be readily applied to a range of chemical reactions.

关键字：Photo-curing 3D printing; Desulfurization; Monolithic catalysts; Stirring reactor; Molybdenum oxide

ISSN号：1383-5866

卷、期、页：卷327

发表日期：2023-12-15

影响因子：0.000000

期刊分区（SCI为中科院分区）：一区

收录情况：SCI（科学引文索引印刷版）,EI（工程索引）,SCIE（科学引文索引网络版）

发表期刊名称：SEPARATION AND PURIFICATION TECHNOLOGY

参与作者：Wu, Yingcheng,He, Jing,Chen, Wenwen,She, Xiaojie,Song, Yanhua,Li, Huaming,Xu, Hui

通讯作者：黄文峰

第一作者：朱文帅

论文类型：期刊论文

论文概要：Wu, Yingcheng,He, Jing,黄文峰,Chen, Wenwen,She, Xiaojie,Song, Yanhua,朱文帅,Li, Huaming,Xu, Hui，Tailored monolithic catalyst and reactor by direct photo-curing 3D printing for oxidative desulfurization of fuels，SEPARATION AND PURIFICATION TECHNOLOGY，2023，卷327

论文题目：Tailored monolithic catalyst and reactor by direct photo-curing 3D printing for oxidative desulfurization of fuels