摘要：A series of basic nitrogen doped carbon hollow spheres (p-N-C) catalysts derived from waste tires were prepared by a green, facile and environmental "leavening" strategy for the catalytic oxidation of pentanethiol. Compared to pristine carbon, the p-N-C has a higher surface curvature conducive to the enrichment of substrates, leading to an excellent catalytic performance. This increased surface curvature of p-N-C was fabricated on the synergistic effect of two foaming agents ((NH4)(2)C2O4 and NaHCO3), and the released gas also endows the spherical shell of p-N-C with a hierarchical porous structure, promoting the accessibility of active sites with pentanethiol. Pyridine-like and pyrrolic-like nitrogen atoms were investigated as reactive sites on the p-N-C to accelerate the electron transfer from sulfur to active surface oxygen and enhance the adsorption/oxidation process. As a result, the optimal p-N-C catalyst exhibits superior adsorption and oxidation performance (99.9%) of pentanethiol, outperforming the "unleavened" catalyst (20.8%). This work offers a new avenue for the fabrication of highly efficient materials for the desulfurization of fuel. (C) 2022 The Authors. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd.

关键字：Carbon hollow spheres; Nitrogen-doping; Waste tires; Leavening strategy; Pentanethiol

ISSN号：1672-5107

卷、期、页：卷: 19期: 4页: 1888-1896

发表日期：2022-08-01

影响因子：4.090000

期刊分区（SCI为中科院分区）：一区

收录情况：SCIE（科学引文索引网络版）

发表期刊名称：PETROLEUM SCIENCE

参与作者：罗静,Zhang, Wen-Feng,Wei, Yan-Chen,Liu, Ji-Xing,Wang, Chao,Zou, Yi-Ru,Ju, Hai-Tao,Mu, Li-Ping,Ji, Hong-Bing

第一作者：巢艳红,朱文帅

论文类型：期刊论文

论文概要：罗静,Zhang, Wen-Feng,Wei, Yan-Chen,Liu, Ji-Xing,Wang, Chao,Zou, Yi-Ru,Ju, Hai-Tao,Mu, Li-Ping,巢艳红,Ji, Hong-Bing,朱文帅，Catalytic oxidation of pentanethiol on basic nitrogen doped carbon hollow spheres derived from waste tires，PETROLEUM SCIENCE，2022，卷: 19期: 4页: 1888-1896

论文题目：Catalytic oxidation of pentanethiol on basic nitrogen doped carbon hollow spheres derived from waste tires